GRAPHITE
Authorisation number: 00A603-00
- Formulation
- Emulsifiable concentrate
- first authorised
- 2023-02-17
- authorised until
- 2028-03-31
- Field of activity
- Fungicide
- Hazard to bees
- no classification recorded
- Trial designation
- 12769-57251-F-0-EC
Active substances
| Active substance | English name | Content | Category | EU approved |
|---|---|---|---|---|
| Prothioconazol | prothioconazole | 0 GL | Wirkstoff | yes |
| Tebuconazol | tebuconazole | 0 GL | Wirkstoff | yes |
Holder and distribution
- Authorisation holder
- SHA1
- Distribution
- SHP
Authorised uses (7)
| Crop | Pest | Area of use | Use no. |
|---|---|---|---|
| rye | leaf spot of wheat, septoria leaf spot of wheat, brown rust (Puccinia recondita f.sp.tritici), powdery mildew (Erysiphe graminis) | Outdoors | 00A603-00/00-002 |
| triticale | leaf spot of wheat, septoria leaf spot of wheat, brown rust (Puccinia recondita f.sp.tritici), powdery mildew (Erysiphe graminis) | Outdoors | 00A603-00/00-003 |
| spring barley | Fusarium species | Outdoors | 00A603-00/00-006 |
| mustard species | black leg of cruzifers (Leptosphaeria maculans) | Outdoors | 00A603-00/00-010 |
| mustard species | black leg of cruzifers (Leptosphaeria maculans) | Outdoors | 00A603-00/00-011 |
| mustard species | Sclerotinia sclerotiorum | Outdoors | 00A603-00/00-012 |
| sunflower, common | Sclerotinia sclerotiorum, grey mould (Botrytis cinerea), Alternaria species (Alternaria spp.), stalk rot of sunflower (Diaporthe helianthi) | Outdoors | 00A603-00/00-013 |
Conditions of use
| Code | Text | Crop | Buffer zone |
|---|---|---|---|
| SS530 | Wear face protection when handling the undiluted product. | – | – |
| SS610 | Wear a rubber apron when handling the undiluted product. | – | – |
| VA271 | When applying the product, a minimum buffer zone of 5 m must be kept to adjacent areas which are used by uninvolved third persons. Alternatively, driftreducing equipment which is registered in the index of 'Loss Reducing Equipment' of 14 October 1993 ("Bundesanzeiger" (Federal Gazette) No 205, p. 9780) as amended, and registered in at least drift-reducing class 50 % can be used for application. In this case, the minimum buffer zone for field crops stated in the BVL publication in the Federal Gaz | – | – |
| NW470 | Where applicable, fluids left over from application, granules and their remains as well as cleansing and rinsing fluids must not be dumped in water. This also applies to indirect entry via the urban or agrarian drainage system and to rain-water and sewage canals. | – | – |
| SF275-VEAC | For the period after application until shortly before harvest in field crops, it must be ensured that long-sleeved working clothes and sturdy footwear are worn during successive work/inspections with direct contact with the treated crops/areas. | – | – |
| SS110-1 | Protective gloves (plant protection) must be worn when handling the undiluted product. | – | – |
| SS2101 | Wear a protective suit against pesticides and sturdy shoes (e.g. rubber boots) when handling the undiluted product. | – | – |
Restrictions
| Code | Text | Crop | Buffer zone |
|---|---|---|---|
| EB001-2 | SP 1: Do not contaminate water with the product or its container (Do not clean application equipment near surface water./Avoid contamination via drains from farmyards and roads). | – | – |
| NN2001 | The product is classified as slightly harmful for populations of relevant beneficial insects. | – | – |
| NW262 | The product is toxic for algae. | – | – |
| NW264 | The product is toxic for fish and aquatic invertebrates. | – | – |
| NW265 | The product is toxic for higher aquatic plants. | – | – |
| SB001 | Avoid any unnecessary contact with the product. Misuse can lead to health damage. | – | – |
| SB005 | If medical advice is needed, have product container or label at hand. | – | – |
| SB010 | Keep out of children's reach. | – | – |
| SB111 | Concerning the requirements for personal protective gear for handling the plant protection product the material safety data sheet and the instructions for use of the plant protection product as well as the guideline "Personal protective gear for handling plant protection prod-ucts" of the Federal Office of Consumer Protection and Food Safety (www.bvl.bund.de) must be observed. | – | – |
| SB166 | Do not eat, drink or smoke when using this product. | – | – |
| SF245-02 | It must be ensured that treated areas/crops may not be entered until the film of the plant protection product has dried. | – | – |
| SS206 | Working clothes (if no specific protective suit is required) and sturdy footwear (e.g. rubber boots) must be worn when applying/handling plant protection products. | – | – |
| WMFG1 | Mode of action (FRAC-Group): G1 | – | – |
| WH952 | The indication identifying the mode of action must be assigned directly to each corresponding name of the active substance as supplementary information on the packaging and in the instructions for use. | – | – |
Notes
- The product is classified as non-hazardous to bees, even when the maximum application rate, or concentration if no application rate is stipulated, as stated for authorisation is applied. (B4)
- The product is classified as non-harmful for populations of relevant beneficial predatory mites and spiders.
Hazard classification (GHS/CLP)
Signal word
- Warning
Hazard pictograms
- GHS07
- GHS08
- GHS09
Hazard statements
- To avoid risks to human health and the environment, comply with the instructions for use.
- Causes skin irritation.
- May cause an allergic skin reaction.
- Causes serious eye irritation.
- May cause respiratory irritation.
- Suspected of damaging the unborn child.
- Very toxic to aquatic life.
- Toxic to aquatic life with long lasting effects.
Precautionary statements
- If medical advice is needed, have product container or label at hand.
- Keep out of reach of children.
- Avoid breathing dust/fume/gas/mist/vapours/spray.
- Use only outdoors or in a well-ventilated area.
- Wear protective gloves/protective clothing/eye protection/face protection.
- IF ON SKIN: Wash with plenty of water/...
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- IF exposed or concerned: Get medical advice/attention.
- Take off contaminated clothing and wash it before reuse.
- Collect spillage.
- Store in a well-ventilated place. Keep container tightly closed.
- Store locked up.
- Dispose of contents/container to ...
Pack sizes
- 1.00 LX 10 (52)
- 5.00 - 25.00 LX 22 (52)
Further information
Data source: PSM-API · Data as of: 2026-08-05
Only the authorisation notice together with the product label and instructions for use is legally binding.